The best place to connect, with the hottest coolant, would be the front of the head.
On the industrial engines the high water temperature shutdown is tapped into the thermostat housing where there is a small removable flange. This would translate to the adapter housing on the marine engine and there appears to be a pipe plug access. Seems as though this could be your source for hot water to run through a heat exchanger. I cant tell what the equivalent low pressure or suction side connection would be on the marine engine but there most likely is one.
I am told all the #12 graders had cabin heaters that were tapped into the cooling system. Can anyone tell me where the coolant lines for the heater attached?